2014 : KINETIKA REAKSI SINTHESIS BIOMATERIAL HIDROXYAPATITE DENGAN JENIS PREKURSOR NITRAT DAN ASETAT

Prof.Dr.Ir. Sugeng Winardi M.Eng


Abstract

KINETIC STUDY OF THE BIOMATERIAS HIDOXYAPATITE SINTHESIS WITH PRECURSOR NITRATE AND ACETATE. Hidroxyapatite (HAp) is one of the biomaterials widely applied in the medical world to make implant tissues of the body, especially bones and teeth so that the purity of the HAp plays a fairly important. In order to obtain high purity HAp, reaction kinetics should be known clearly. TG-DTA is method used to obtain the reaction kinetics of HAp. TG-DTA analyzes were conducted on precursors acetate and nitrate. TG-DTA method is carried out by heating HAp precursor with variation heating rate 10, 15, 17, and 20 C/min respectively. The results of TG-DTA showed decomposition precursor acetate and nitrate formed HAp occurs on temperature 659 C and 560 C respectively. The results of the fitting kinetic showed activation energy of the HAp formation on acetate precursors about 161.56 kJ/mol with Normal Grain Growth kinetic model whereas the nitrate precursor about 374 kJ/mol with Johnson-Mehl-Avrami kinetic model.